[(Methylcarbamothioyl)disulfanyl]methyl N-methylcarbamodithioate
نویسندگان
چکیده
The title compound, C(5)H(10)N(2)S(5), was unintentionally obtained as the product of an attempted synthesis of a methyl-carbamodithioic acid using methyl-amine and carbon disulfide. In the mol-ecule, two dithio-carbamate groups are bridged by a -CH(2)S- unit. The C-S-S-C torsion angle is -90.13 (11)°. The crystal structure is stabilized by N-H⋯S inter-actions between neighbouring mol-ecules. An intra-molecular N-H⋯S hydrogen bond also occurs.
منابع مشابه
1-Methyl-2-({[(2-methylphenyl)methyl]disulfanyl}methyl)benzene
In the title disulfide, C(16)H(18)S(2), the mol-ecule is twisted about the central S-S bond [the C-S-S-C torsion angle = 93.24 (7)°] and the dihedral angle between the benzene rings is 72.84 (7)°, indicating an almost orthogonal relationship; the methyl groups are orientated to the same side of the mol-ecule. The crystal packing features C-H⋯.π inter-actions which consolidate a three-dimensiona...
متن کاملN-Ethyl-N-phenyl{[ethyl(phenyl)carbamothioyl]disulfanyl}carbothioamide
The asymmetric unit of the title compound, C(18)H(20)N(2)S(4), contains one half-mol-ecule, the complete molecule being generated by a twofold rotation axis. The plane through the NCS(2) group [maximum deviation = 0.01 (7) Å] is orthogonal to the phenyl ring, forming a dihedral angle of 89.4 (3)°. The crystal structure is stabilized by inter-molecular C-H⋯π inter-actions.
متن کامل2-[(2-Carboxyphenyl)disulfanyl]benzoic acid–4,4′-bipyridyl N,N′-dioxide (1/2)
In the title 2:1 adduct, C(14)H(10)O(4)S(2)·0.5C(10)H(8)N(2)O(2), which arose from an unexpected oxidation of a precursor, the dihedral angle between the aromatic rings in the disulfide is 82.51 (11)°. In the crystal, the molecules are linked by O-H⋯O, O-H⋯N and C-H⋯O interactions, generating sheets.
متن کاملDi-μ-bromido-bis({2-[(4,6-dimethylpyrimidin-2-yl)disulfanyl]-4,6-dimethylpyrimidine-κ2 N 1,S 2}copper(I))
The title dinuclear complex, [Cu(2)Br(2)(C(12)H(14)N(4)S(2))(2)], is located about an inversion center. The Cu(I) ion is coordinated in a distorted tetra-hedral geometry by two bridging Br atoms in addition to an N and an S atom from the 2-[(4,6-dimethyl-pyrimidin-2-yl)disulfan-yl]-4,6-dimethyl-pyrimidine ligand. In the crystal, π-π stacking inter-actions are observed with a centroid-centroid d...
متن کامل(2-Hydroxyethyl)(propyl)azanium 2-[(2-carboxyphenyl)disulfanyl]benzoate monohydrate
With the exception of the terminal hydr-oxy group [N-C-C-O = 53.8 (5)°], the cation of the title salt hydrate, C(5)H(14)NO(+)·C(14)H(9)O(4)S(2) (-.)H(2)O, is a straight chain. A twisted conformation is found for the anion [C-S-S-C = -87.44 (16)°]. In the crystal, the anions self-assemble into a helical supra-molecular chain via charge-assisted O-H⋯O(c) hydrogen bonds. These chains are connected...
متن کامل